Determination of oxygen triple isotope ratios of silicates without cryogenic separation of NF3- technique with application to analyses of technical O2 gas and meteorite classification.

A novel technique is described to determine Delta'(17)O(TFL) with high accuracy and precision by using infrared (IR) laser fluorination with F(2) as the reaction gas. The technique includes precise monitoring of the intensity ratio of the (14)NF(2)+ (m/z 52) to O(2) signals. The correlation between the intensity of (14)NF(2) + and positive error in delta(17)O(VSMOW) allows correction of measured data to obtain reliable Delta'(17)O(TFL) values. The resultant error in Delta'(17)O(TFL) of a single measurement after correction is in the range of +/-0.06 per thousand, i.e. sufficiently small to permit the technique to be useful for meteorite classification. Our data for technical O(2), in combination with literature data, suggest a negative anomaly of tropospheric air O(2) with Delta'(17)O(TFL) = -0.344 +/- 0.015 per thousand (1sigma). Copyright 2007 John Wiley & Sons, Ltd.