| Literature DB >> 17940649 |
Zai-Chao Zhang1, Song Gao, Li-Min Zheng.
Abstract
A cobalt diphosphonate Co(H(2)O){C(5)H(5)N-CH(2)CH(OH)(PO(3))(PO(3)H)} (1) has been synthesized under hydrothermal conditions. It shows a novel type of double chain structure in which one of the two CPO(3) terminus caps on top of the {Co(2)(micro-O)2} dimer while the other connects the adjacent {Co(2)(micro-O)2} dimers into a chain. The magnetization measurements reveal that dominant antiferromagnetic interactions are mediated between the magnetic centers and the compound experiences a field-induced magnetic transition at low temperature with H(c) of ca. 15 kOe at 1.8 K.Entities:
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Year: 2007 PMID: 17940649 DOI: 10.1039/b709474d
Source DB: PubMed Journal: Dalton Trans ISSN: 1477-9226 Impact factor: 4.390