| Literature DB >> 17937780 |
Marc J Bazin, Helen Shi, Jeannine Delaney, Billie Kline, Zhendong Zhu, Cyrille Kuhn, Francoise Berlioz, Kathleen A Farley, Gwen Fate, Wing Lam, Gregory S Walker, Linning Yu, Michael P Pollastri.
Abstract
Major metabolites of dimethylaminoantipyrine have been synthesized using iron ortho-nitrophenylporphyrin chloride as biomimetic catalyst. Reactivity of iron tetrakis-ortho-nitrophenylporphyrin chloride [Fe(TNO2PP)Cl] has been compared with iron tetrakis-pentafluorophenylporphyrin chloride and iron tetrakis-2,6-dichlorophenylporphyrin chloride using various oxidants such as hydrogen peroxide, iodosobenzene, and cumene hydroperoxide in either protic or aprotic solvent. Effect of imidazole has been showed on the reactivity of Fe(TNO2PP)Cl/cumene hydroperoxide system.Entities:
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Year: 2007 PMID： 17937780 DOI： 10.1111/j.1747-0285.2007.00568.x
Source DB: PubMed Journal: Chem Biol Drug Des ISSN： 1747-0277 Impact factor: 2.817