Literature DB >> 17930190

Dielectric spectroscopy in benzophenone: the beta relaxation and its relation to the mode-coupling Cole-Cole peak.

L C Pardo1, P Lunkenheimer, A Loidl.   

Abstract

We report a thorough characterization of the glassy dynamics of benzophenone by broadband dielectric spectroscopy. We detect a well-pronounced beta relaxation peak developing into an excess wing with increasing temperature. A previous analysis of results from Optical-Kerr-effect measurements of this material within the mode-coupling theory revealed a high-frequency Cole-Cole peak. We address the question if this phenomenon also may explain the Johari-Goldstein beta relaxation, a so-far unexplained spectral feature inherent to glass-forming matter, mainly observed in dielectric spectra. Our results demonstrate that according to the present status of theory, both spectral features seem not to be directly related.

Entities:  

Year:  2007        PMID: 17930190     DOI: 10.1103/PhysRevE.76.030502

Source DB:  PubMed          Journal:  Phys Rev E Stat Nonlin Soft Matter Phys        ISSN: 1539-3755


  4 in total

1.  Dielectric and conductivity relaxation in mixtures of glycerol with LiCl.

Authors:  M Köhler; P Lunkenheimer; A Loidl
Journal:  Eur Phys J E Soft Matter       Date:  2008-08-29       Impact factor: 1.890

2.  Characteristic length scales of the secondary relaxations in glass-forming glycerol.

Authors:  S Gupta; E Mamontov; N Jalarvo; L Stingaciu; M Ohl
Journal:  Eur Phys J E Soft Matter       Date:  2016-03-29       Impact factor: 1.890

3.  Coincident Correlation between Vibrational Dynamics and Primary Relaxation of Polymers with Strong or Weak Johari-Goldstein Relaxation.

Authors:  Antonio Tripodo; Francesco Puosi; Marco Malvaldi; Simone Capaccioli; Dino Leporini
Journal:  Polymers (Basel)       Date:  2020-03-31       Impact factor: 4.329

4.  Low-Frequency (Gigahertz to Terahertz) Depolarized Raman Scattering Off n-Alkanes, Cycloalkanes, and Six-Membered Rings: A Physical Interpretation.

Authors:  Andrew J Farrell; Mario González-Jiménez; Gopakumar Ramakrishnan; Klaas Wynne
Journal:  J Phys Chem B       Date:  2020-08-21       Impact factor: 2.991

  4 in total

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