Literature DB >> 17925966

Insertion of benzyl isocyanide into a Zr-P bond and rearrangement. Atom-economical synthesis of a phosphaalkene.

Samantha N MacMillan1, Joseph M Tanski, Rory Waterman.   

Abstract

Reaction of (N(3)N)ZrPHPh (N(3)N=N(CH(2)CH(2)NSiMe(3))(3)(3-)) with PhCH(2)N[triple bond]C affords the 1,1-insertion product (N(3)N)Zr[C(PHPh)=NCH(2)Ph], which thermally rearranges to the phosphaalkene-containing complex, (N(3)N)Zr[N(CH(2)Ph)C(H)=PPh].

Entities:  

Year:  2007        PMID： 17925966     DOI： 10.1039/b709506f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  {N,N-Bis[2-(trimethyl-silylamino)eth-yl]-N'-(trimethyl-silyl)ethane-1,2-diamin-ato(3-)-κN}methyl-zirconium(IV).

Authors:  Samantha N Macmillan; Joseph M Tanski; Rory Waterman
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-02-15

2.  Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids.

Authors:  Alisha Rani Tripathy; Girish Suresh Yedase; Veera Reddy Yatham
Journal:  RSC Adv       Date:  2021-07-21       Impact factor: 4.036
  2 in total

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