Literature DB >> 17925959

Versatile direct dehydrative approach for diaryliodonium(III) salts in fluoroalcohol media.

Toshifumi Dohi1, Motoki Ito, Koji Morimoto, Yutaka Minamitsuji, Naoko Takenaga, Yasuyuki Kita.   

Abstract

We have found that the use of fluoroalcohol media greatly enhanced the efficiency and scope of the direct dehydrative condensation of arenes and hypervalent iodine(III) compounds; the present clean method has a broad range of applicability as well as unique selectivity in the aromatic substrates, and is highly efficient even in polymer functionalization.

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Year:  2007        PMID： 17925959     DOI： 10.1039/b708802g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

Review 1.  Chemistry of polyvalent iodine.

Authors:  Viktor V Zhdankin; Peter J Stang
Journal:  Chem Rev       Date:  2008-12       Impact factor: 60.622

2.  Enhanced reactivity of [hydroxy(tosyloxy)iodo]benzene in fluoroalcohol media. Efficient direct synthesis of thienyl(aryl)iodonium salts.

Authors:  Motoki Ito; Chieko Ogawa; Nobutaka Yamaoka; Hiromichi Fujioka; Toshifumi Dohi; Yasuyuki Kita
Journal:  Molecules       Date:  2010-03-17       Impact factor: 4.411

3.  Synthesis of Uracil-Iodonium(III) Salts for Practical Utilization as Nucleobase Synthetic Modules.

Authors:  Naoko Takenaga; Takumi Hayashi; Shohei Ueda; Hiroyuki Satake; Yoichi Yamada; Tetsuya Kodama; And Toshifumi Dohi
Journal:  Molecules       Date:  2019-08-21       Impact factor: 4.411

Review 4.  Heteroaryliodonium(III) Salts as Highly Reactive Electrophiles.

Authors:  Naoko Takenaga; Ravi Kumar; Toshifumi Dohi
Journal:  Front Chem       Date:  2020-11-20       Impact factor: 5.221

5.  Palladium-catalyzed direct β-arylation of ketones with diaryliodonium salts: a stoichiometric heavy metal-free and user-friendly approach.

Authors:  Zhongxing Huang; Quynh P Sam; Guangbin Dong
Journal:  Chem Sci       Date:  2015-06-17       Impact factor: 9.825

6.  Hypercoordinate iodine for catalytic asymmetric diamination of styrene: insights into the mechanism, role of solvent, and stereoinduction.

Authors:  A Sreenithya; Christopher M Hadad; Raghavan B Sunoj
Journal:  Chem Sci       Date:  2019-06-10       Impact factor: 9.825

7.  Nucleophilic Arylation of Halopurines Facilitated by Brønsted Acid in Fluoroalcohol.

Authors:  Naoko Takenaga; Toshitaka Shoji; Takayuki Menjo; Akiko Hirai; Shohei Ueda; Kotaro Kikushima; Tomonori Hanasaki; Toshifumi Dohi
Journal:  Molecules       Date:  2019-10-23       Impact factor: 4.411
  7 in total

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