Literature DB >> 17915891

Solvent-controlled Csp2-->O silyl migration: the "one-pot" synthesis of 2,3-disubsituted thiophenes.

Nelmi O Devarie-Baez1, Brian J Shuhler, Hua Wang, Ming Xian.   

Abstract

An effective "one-pot" synthesis of disubstituted thiophene derivatives employing 3-bromo-2-silyl thiophenes has been developed. A solvent-controlled [1,4] Csp2-->O silyl migration was involved as the key step in this process.

Entities:  

Year:  2007        PMID： 17915891     DOI： 10.1021/ol702149c

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Ortho-TMS benzaldehyde: an effective linchpin for type II anion relay chemistry (ARC).

Authors:  Amos B Smith; Won-Suk Kim; William M Wuest
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

Review 2.  Evolution of multi-component anion relay chemistry (ARC): construction of architecturally complex natural and unnatural products.

Authors:  Amos B Smith; William M Wuest
Journal:  Chem Commun (Camb)       Date:  2008-09-30       Impact factor: 6.222

3.  Multicomponent type II anion relay chemistry (ARC): one-pot syntheses of 2,3-disubstituted furans and thiophenes.

Authors:  Nelmi O Devarie-Baez; Won-Suk Kim; Amos B Smith; Ming Xian
Journal:  Org Lett       Date:  2009-04-16       Impact factor: 6.005

4.  An efficient synthesis of N-substituted 3-nitrothiophen-2-amines.

Authors:  Sundaravel Vivek Kumar; Shanmugam Muthusubramanian; J Carlos Menéndez; Subbu Perumal
Journal:  Beilstein J Org Chem       Date:  2015-09-22       Impact factor: 2.883
  4 in total

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