Literature DB >> 17912393

Spoilt for choice: assessing phase behavior models for the evolution of homochirality.

Donna G Blackmond1, Martin Klussmann.   

Abstract

The observation of single chirality in biological systems has intrigued scientists for more than one hundred years. Here we discuss several recent experimental studies showing amplification of enantiomeric excess based on amino acid phase behavior. Comparing observations of solution-solid and gas-solid phase transitions highlights the underlying fundamental physical chemistry principles that rationalize the observed enantioenrichment in both cases.

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Year:  2007        PMID: 17912393     DOI: 10.1039/b709314b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  8 in total

Review 1.  The origin of biological homochirality.

Authors:  Donna G Blackmond
Journal:  Cold Spring Harb Perspect Biol       Date:  2010-03-31       Impact factor: 10.005

2.  Thermodynamic mechanism for solution phase chiral amplification via a lattice model.

Authors:  Thomas G Lombardo; Frank H Stillinger; Pablo G Debenedetti
Journal:  Proc Natl Acad Sci U S A       Date:  2009-04-23       Impact factor: 11.205

3.  Isovaline monohydrate.

Authors:  Ray J Butcher; Greg Brewer; Aaron S Burton; Jason P Dworkin
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-11-27

4.  Adsorption-induced auto-amplification of enantiomeric excess on an achiral surface.

Authors:  Yongju Yun; Andrew J Gellman
Journal:  Nat Chem       Date:  2015-05-04       Impact factor: 24.427

Review 5.  Transmission of chirality through space and across length scales.

Authors:  Sarah M Morrow; Andrew J Bissette; Stephen P Fletcher
Journal:  Nat Nanotechnol       Date:  2017-05-05       Impact factor: 39.213

6.  Deracemization of amino acids by partial sublimation and via homochiral self-organization.

Authors:  Arkadii V Tarasevych; Alexander E Sorochinsky; Valery P Kukhar; Jean-Claude Guillemin
Journal:  Orig Life Evol Biosph       Date:  2013-05-21       Impact factor: 1.950

7.  2-Methyl-aspartic acid monohydrate.

Authors:  Greg Brewer; Aaron S Burton; Jason P Dworkin; Ray J Butcher
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-11-30

Review 8.  Recommended Tests for the Self-Disproportionation of Enantiomers (SDE) to Ensure Accurate Reporting of the Stereochemical Outcome of Enantioselective Reactions.

Authors:  Jianlin Han; Alicja Wzorek; Karel D Klika; Vadim A Soloshonok
Journal:  Molecules       Date:  2021-05-07       Impact factor: 4.411

  8 in total

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