| Literature DB >> 17910508 |
Alexander D Dilman1, Dmitry E Arkhipov, Vitalij V Levin, Pavel A Belyakov, Alexander A Korlyukov, Marina I Struchkova, Vladimir A Tartakovsky.
Abstract
A method for the nucleophilic trifluoromethylation of salicyl aldimines, which do not contain an activating group at the nitrogen atom, has been described. The reaction proceeds through the initial generation of intramolecular boron complex followed by interaction with Me3SiCF3 activated by sodium acetate.Entities:
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Year: 2007 PMID： 17910508 DOI： 10.1021/jo701734d
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354