Evaluation of the seasonal variation on the geochemical parameters and quality assessment of the groundwater in the proximity of River Cooum, Chennai, India.

The seasonal variations of the chemical budget of ions were determined from the hydrochemical investigation of the groundwater. Though the effect of monsoon does not change the order of abundance of cations, but it does change the concentration of various ions and it is found that there was a considerable change in the case of all major ions. The unique characteristic of the ground water is the linear relationship among the principal ions. Hydrochemical characteristics of ions in the groundwater were studied using 1:1 equiline diagrams. The nature of the water samples were determined using the piper diagram. The correlation studies and R-mode factor analysis were carried out on the various groundwater parameters. The study of factor scores reveals the extent of influence of each factors on the overall water chemistry at each sampling stations. The trace metal concentration in the water was determined. The quality of the groundwater in the study area has been assessed using Percent sodium, SAR and Wilcox diagrams. The groundwater results of the premonsoon shows the dominance of excessive evaporation, silicate weathering and anthropogenic activities whereas in postmonsoon, dilution predominates over that of other factors.