Literature DB >> 17854199

Room temperature-stable electride as a synthetic organic reagent: application to pinacol coupling reaction in aqueous media.

Haritha Buchammagari1, Yoshitake Toda, Masahiro Hirano, Hideo Hosono, Daisuke Takeuchi, Kohtaro Osakada.   

Abstract

Room temperature-stable inorganic electride [Ca(24)Al(28)O(68)](4+)4e(-) was employed for a pinacol coupling reaction in aqueous media. Ca-Al-O gel formed by the destruction of the crystal structure of an electride by water media played a key role in transferring the electron to electrophilic aldehydes. Aromatic aldehydes reacted smoothly with moderate to high yields.

Entities:  

Year:  2007        PMID： 17854199     DOI： 10.1021/ol701885p

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  9 in total

1.  "On-water" catalyst-free ecofriendly synthesis of the hantzsch dihydropyridines.

Authors:  Amit Pramanik; Manabendra Saha; Sanjay Bhar
Journal:  ISRN Org Chem       Date:  2012-08-12

2.  Chemoselective reduction and oxidation of ketones in water through control of the electron transfer pathway.

Authors:  Sun Min Kim; Ho Sung Yoo; Hideo Hosono; Jung Woon Yang; Sung Wng Kim
Journal:  Sci Rep       Date:  2015-05-28       Impact factor: 4.379

3.  Single step synthesis of highly conductive room-temperature stable cation-substituted mayenite electride target and thin film.

Authors:  Karim Khan; Ayesha Khan Tareen; Usman Khan; Adeela Nairan; Sayed Elshahat; Naseer Muhammad; Muhammad Saeed; Ashish Yadav; Luigi Bibbò; Zhengbiao Ouyang
Journal:  Sci Rep       Date:  2019-03-21       Impact factor: 4.379

4.  Comparison Between Electride Characteristics of Li3@B40 and Li3@C60.

Authors:  Prasenjit Das; Pratim Kumar Chattaraj
Journal:  Front Chem       Date:  2021-03-15       Impact factor: 5.221

5.  Mayenite Synthesis from Hydroxide Precursors: Structure Formation and Active Sites on Its Surface.

Authors:  Aleksandr V Kapishnikov; Roman M Kenzhin; Anton P Koskin; Alexander M Volodin; Pavel V Geydt
Journal:  Materials (Basel)       Date:  2022-01-20       Impact factor: 3.623

6.  Facile metal-free reduction-based synthesis of pristine and cation-doped conductive mayenite.

Authors:  Karim Khan; Ayesha Khan Tareen; Sayed Elshahat; Naseer Muhammad; Jia Li; Israa Aboodd; Luigi Bibbò; Ashish Yadav; Rizwan Ur Rehman Sagar; Usman Khan; Zhengbiao Ouyang
Journal:  RSC Adv       Date:  2018-07-04       Impact factor: 4.036

7.  Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction.

Authors:  Craig S Day; Cuong Dat Do; Carlota Odena; Jordi Benet-Buchholz; Liang Xu; Cina Foroutan-Nejad; Kathrin H Hopmann; Ruben Martin
Journal:  J Am Chem Soc       Date:  2022-07-13       Impact factor: 16.383

8.  Water- and acid-stable self-passivated dihafnium sulfide electride and its persistent electrocatalytic reaction.

Authors:  Se Hwang Kang; Joonho Bang; Kyungwha Chung; Chandani N Nandadasa; Gyeongtak Han; Subin Lee; Kyu Hyoung Lee; Kimoon Lee; Yanming Ma; Sang Ho Oh; Seong-Gon Kim; Young-Min Kim; Sung Wng Kim
Journal:  Sci Adv       Date:  2020-06-05       Impact factor: 14.136

9.  Diastereoselective synthesis of cyclopentanediols by InCl 3/Al mediated intramolecular pinacol coupling reaction in aqueous media.

Authors:  Yunhua Chen; Jieping Wan; Chunyan Wang; Cuirong Sun
Journal:  Molecules       Date:  2008-10-27       Impact factor: 4.411
  9 in total

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