Literature DB >> 17844747

A new zinc-zinc-bonded compound with a dianionic alpha-diimine ligand: synthesis and structure of [Na(THF)2]2 x [LZn-ZnL] (L = [(2,6-(i)Pr2C6H3)N(Me)C]2(2-)).

Xiao-Juan Yang1, Jie Yu, Yanyan Liu, Yaoming Xie, Henry F Schaefer, Yongmin Liang, Biao Wu.   

Abstract

The synthesis and structure of a Zn-Zn-bonded compound supported by a doubly reduced alpha-diimine ligand, [Na(THF)2]2 x [LZn-ZnL] (L = [(2,6-(i)Pr2C6H3)N(Me)C]2(2-)) are reported, with a Zn-Zn bond length of 2.399(1) angstroms.

Entities:  

Year:  2007        PMID： 17844747     DOI： 10.1039/b703200e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.

Authors:  Ross Campbell; Daniel Cannon; Pablo García-Álvarez; Alan R Kennedy; Robert E Mulvey; Stuart D Robertson; Jörg Sassmannshausen; Tell Tuttle
Journal:  J Am Chem Soc       Date:  2011-08-04       Impact factor: 15.419

2.  Electronic and Geometric Structures of Paramagnetic Diazadiene Complexes of Lithium and Sodium.

Authors:  Haleh H Haeri; Ramesh Duraisamy; Nicole Harmgarth; Phil Liebing; Volker Lorenz; Dariush Hinderberger; Frank T Edelmann
Journal:  ChemistryOpen       Date:  2018-09-05       Impact factor: 2.911
  2 in total

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