Literature DB >> 17812259

Tetramesityldisilene, a stable compound containing a silicon-silicon double bond.

R West, M J Fink, J Michl.   

Abstract

Irradiation of 2,2-bis(2,4,6-trimethylphenyl)hexamethyltrisilane in hydrocarbon solution produces tetramesityldisilene, which can be isolated as a yellow-orange solid stable to room temperature and above in the absence of air. Like the olefins of carbon chemistry, tetramesityldisilene undergoes addition reactions across the silicon-silicon double bond.

Entities:  

Year:  1981        PMID: 17812259     DOI: 10.1126/science.214.4527.1343

Source DB:  PubMed          Journal:  Science        ISSN: 0036-8075            Impact factor:   47.728


  20 in total

1.  Main group chemistry: Small silicon oxides isolated.

Authors:  Yitzhak Apeloig
Journal:  Nat Chem       Date:  2015-06       Impact factor: 24.427

2.  A stable germanone as the first isolated heavy ketone with a terminal oxygen atom.

Authors:  Liangchun Li; Tomohide Fukawa; Tsukasa Matsuo; Daisuke Hashizume; Hiroyuki Fueno; Kazuyoshi Tanaka; Kohei Tamao
Journal:  Nat Chem       Date:  2012-03-25       Impact factor: 24.427

3.  Main-group elements as transition metals.

Authors:  Philip P Power
Journal:  Nature       Date:  2010-01-14       Impact factor: 49.962

4.  Polymerization of silanes through dehydrogenative Si-Si bond formation on metal surfaces.

Authors:  Lacheng Liu; Henning Klaasen; Melanie C Witteler; Bertram Schulze Lammers; Alexander Timmer; Huihui Kong; Harry Mönig; Hong-Ying Gao; Johannes Neugebauer; Harald Fuchs; Armido Studer
Journal:  Nat Chem       Date:  2021-03-29       Impact factor: 24.427

Review 5.  Bonding and structure of disilenes and related unsaturated group-14 element compounds.

Authors:  Mitsuo Kira
Journal:  Proc Jpn Acad Ser B Phys Biol Sci       Date:  2012       Impact factor: 3.493

6.  Structural Snapshots in Reversible Phosphinidene Transfer: Synthetic, Structural, and Reaction Chemistry of a Sn═P Double Bond.

Authors:  Malte Fischer; Matthew M D Roy; Lewis L Wales; Mathias A Ellwanger; Andreas Heilmann; Simon Aldridge
Journal:  J Am Chem Soc       Date:  2022-05-10       Impact factor: 16.383

Review 7.  π-Electron systems containing Si=Si double bonds.

Authors:  Tsukasa Matsuo; Naoki Hayakawa
Journal:  Sci Technol Adv Mater       Date:  2018-02-07       Impact factor: 8.090

Review 8.  Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis.

Authors:  Franziska Hanusch; Lisa Groll; Shigeyoshi Inoue
Journal:  Chem Sci       Date:  2020-08-03       Impact factor: 9.825

Review 9.  Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds.

Authors:  Abir Sarbajna; V S V S N Swamy; Viktoria H Gessner
Journal:  Chem Sci       Date:  2020-07-17       Impact factor: 9.825

Review 10.  Disila- and digermabenzenes.

Authors:  Takahiro Sasamori
Journal:  Chem Sci       Date:  2021-03-26       Impact factor: 9.825

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