Literature DB >> 17808644

Ammonioborite: new borate polyion and its structure.

S Merlino, F Sartori.   

Abstract

The mineral ammonioborite is monoclinic with unit cell dimensions (in angstroms): a = 25.27, b = 9.65, and c = 11.56; beta = 94 degrees 17', and the space group is C 2/c. Analysis of the crystal structure revealed the crystallo-chemical formula (NH(4))(3)B(15)O(20)(OH)(8).4H(2)O, with four such formula units in the unit cell. The basic structural unit is the double ring consisting of one BO(4) tetrahedron and four BO(3) triangles: in ammonioborite three of these units are connected to give trimeric ions [B(15)O(20)(OH)(8)](3-).

Year:  1971        PMID: 17808644     DOI: 10.1126/science.171.3969.377

Source DB:  PubMed          Journal:  Science        ISSN: 0036-8075            Impact factor:   47.728


  1 in total

1.  Expanding the chemistry of borates with functional [BO2]- anions.

Authors:  Chunmei Huang; Miriding Mutailipu; Fangfang Zhang; Kent J Griffith; Cong Hu; Zhihua Yang; John M Griffin; Kenneth R Poeppelmeier; Shilie Pan
Journal:  Nat Commun       Date:  2021-05-10       Impact factor: 14.919

  1 in total

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