Literature DB >> 17748353

Do hydrofluorocarbons destroy stratospheric ozone?

A R Ravishankara, A A Turnipseed, N R Jensen, S Barone, M Mills, C J Howard, S Solomon.   

Abstract

Hydrofluorocarbons, many of which contain a CF(3) group, are one of the major substitutes for the chlorofluorocarbons and halons that are being phased out because they contribute to stratospheric ozone depletion. It is critical to ensure that CF(3) groups do not cause significant ozone depletion. The rate coefficients for the key reactions that determine the efficiency of the CF(3) radical as a catalyst for ozone loss in the stratosphere have been measured and used in a model to calculate the possible depletion of ozone. From these results, it is concluded that the ozone depletion potentials related to the presence of the CF(3) group in hydrofluorocarbons are negligibly small.

Entities:  

Year:  1994        PMID: 17748353     DOI: 10.1126/science.263.5143.71

Source DB:  PubMed          Journal:  Science        ISSN: 0036-8075            Impact factor:   47.728


  11 in total

1.  Theoretical investigation of the gas-phase reactions of CF2ClC(O)OCH3 with the hydroxyl radical and the chlorine atom at 298 K.

Authors:  Bhupesh Kumar Mishra; Arup Kumar Chakrabartty; Ramesh Chandra Deka
Journal:  J Mol Model       Date:  2013-05-08       Impact factor: 1.810

2.  Theoretical investigation of the mechanisms and dynamics of the reaction CHF2OCF 2CHFCl+Cl.

Authors:  Fengyang Bai; Yanqiu Sun; Xu Wang; Ziman Jia; Rongshun Wang; Xiumei Pan
Journal:  J Mol Model       Date:  2014-08-17       Impact factor: 1.810

3.  Ab initio studies on the decomposition kinetics of CF3OCF2O radical.

Authors:  Hari Ji Singh; Bhupesh Kumar Mishra
Journal:  J Mol Model       Date:  2010-05-19       Impact factor: 1.810

4.  Ab initio studies on the reactivity of the CF3OCH 2O radical: thermal decomposition vs. reaction with O2.

Authors:  Hari Ji Singh; Bhupesh Kumar Mishra
Journal:  J Mol Model       Date:  2010-02-20       Impact factor: 1.810

5.  Computational study of H-abstraction reactions from CH3OCH2CH2Cl/CH3CH2OCH2CH2Cl by Cl atom and OH radical and fate of alkoxy radicals.

Authors:  Jin-Ting Ye; Feng-Yang Bai; Xiu-Mei Pan
Journal:  Environ Sci Pollut Res Int       Date:  2016-09-10       Impact factor: 4.223

6.  Theoretical investigation on the atmospheric fate of CF3C(O)OCH 2O radical: alpha-ester rearrangement vs oxidation at 298 K.

Authors:  Bhupesh Kumar Mishra
Journal:  J Mol Model       Date:  2014-09-11       Impact factor: 1.810

7.  Direct dynamics simulations of the hydrogen abstraction reaction Cl + CF₃CF₂CH₂OH.

Authors:  Ang-Yang Yu; Hong-Xing Zhang
Journal:  J Mol Model       Date:  2013-08-14       Impact factor: 1.810

8.  Efficacy and safety of Qi-Wei-Qing-Yan aerosol in treatment of acute pharyngitis (lung-stomach excess-heat syndrome): study protocol for a randomized controlled trial.

Authors:  Hong-li Jiang; Bin She; Wei Liu; Bing Mao; Ju-ying Zhang
Journal:  Trials       Date:  2016-02-19       Impact factor: 2.279

9.  Theoretical insight into OH- and Cl-initiated oxidation of CF3OCH(CF3)2 and CF3OCF2CF2H &fate of CF3OC(X•)(CF3)2 and CF3OCF2CF2X• radicals (X=O, O2).

Authors:  Feng-Yang Bai; Yuan Ma; Shuang Lv; Xiu-Mei Pan; Xiu-Juan Jia
Journal:  Sci Rep       Date:  2017-01-09       Impact factor: 4.379

Review 10.  Environmental sustainability in anaesthesia and critical care.

Authors:  Forbes McGain; Jane Muret; Cathy Lawson; Jodi D Sherman
Journal:  Br J Anaesth       Date:  2020-08-12       Impact factor: 9.166

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