Literature DB >> 17728883

Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-carboethoxy-2-carboxylatoazulene ligands.

Mikhail V Barybin1, Malcolm H Chisholm, Nathan J Patmore, Randall E Robinson, Namrata Singh.   

Abstract

The preparation and molecular structure of a W2(4+)-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand pi-M2delta-ligand pi conjugation.

Entities:  

Year:  2007        PMID： 17728883     DOI： 10.1039/b708746b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  The remarkable influence of M2delta to thienyl pi conjugation in oligothiophenes incorporating MM quadruple bonds.

Authors:  G T Burdzinski; M H Chisholm; P-T Chou; Y-H Chou; F Feil; J C Gallucci; Y Ghosh; T L Gustafson; M-L Ho; Y Liu; R Ramnauth; C Turro
Journal:  Proc Natl Acad Sci U S A       Date:  2008-10-01       Impact factor: 11.205
  1 in total

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