Literature DB >> 17723243

[FeIII(SR)4]1- complexes can be synthesized by the direct reaction of thiolates with FeCl3.

Sechin Chang1, Stephen A Koch.   

Abstract

It is shown that the previously characterized [Fe(III)(SR)(4)](1-) (R=Et, i-Pr, Ph) complexes can be synthesized by the direct reaction of 4equiv. of LiSR with FeCl(3) in DMF solution. [Fe(III)(SR)(4)](1-) complexes are synthetic analogs for the [Fe(III)(S-Cys)(4)] center in rubredoxin proteins.

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Year:  2007        PMID： 17723243      PMCID： PMC2128701          DOI： 10.1016/j.jinorgbio.2007.07.004

Source DB:  PubMed          Journal:  J Inorg Biochem        ISSN： 0162-0134            Impact factor:   4.155


  6 in total

1.  Evidence for Charge-Dipole Effects in the Rubredoxin Model Compound [(CH(3))(4)N](2)Fe[SCH(2)CON(CH(3))(2)](4).

Authors:  K. Bose; J. Huang; B. S. Haggerty; A. L. Rheingold; R. J. Salm; M. A. Walters
Journal:  Inorg Chem       Date:  1997-09-24       Impact factor: 5.165

Review 2.  Synthetic analogues of the active sites of iron-sulfur proteins.

Authors:  P Venkateswara Rao; R H Holm
Journal:  Chem Rev       Date:  2004-02       Impact factor: 60.622

3.  Synthetic analogues of the active sites of iron-sulfur proteins. 14. Synthesis, properties, and structures of bis(o-xylyl-alpha,alpha'-dithiolato)ferrate(II, III) anions, analogues of oxidized and reduced rubredoxin sites.

Authors:  R W Lane; J A Ibers; R B Frankel; G C Papaefthymiou; R H Holm
Journal:  J Am Chem Soc       Date:  1977-01-05       Impact factor: 15.419

4.  Rubredoxin in crystalline state.

Authors:  L C Sieker; R E Stenkamp; J LeGall
Journal:  Methods Enzymol       Date:  1994       Impact factor: 1.600

5.  Cooperativity and intermediates in the equilibrium reactions of Fe(II,III) with ethanethiolate in N-methylformamide solution.

Authors:  Patrick Frank; Keith O Hodgson
Journal:  J Biol Inorg Chem       Date:  2005-04-29       Impact factor: 3.358

6.  Synthetic analogs of active sites of iron-sulfur proteins: bis (o-xylyldithiolato) ferrate (III) monoanion, a structurally unconstrained model for the rubredoxin Fe-S4 unit.

Authors:  R W Lane; J A Ibers; R B Frankel; R H Holm
Journal:  Proc Natl Acad Sci U S A       Date:  1975-08       Impact factor: 11.205
  6 in total

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