Literature DB >> 17713917

Metal-catalyzed silylene transfer to imines: synthesis and reactivity of silaaziridines.

Zulimar Nevárez1, K A Woerpel.   

Abstract

Metal-catalyzed silylene transfer to imines provides an efficient synthesis of silaaziridines. These strained cyclic silanes undergo selective bond-forming reactions, permitting the synthesis of nitrogen-containing compounds after protodesilylation of the resulting vinyl silane.

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Year:  2007        PMID： 17713917     DOI： 10.1021/ol701424a

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Formation and utility of azasilacyclopentadienes derived from silacyclopropenes and nitriles.

Authors:  Laura L Anderson; K A Woerpel
Journal:  Org Lett       Date:  2009-01-15       Impact factor: 6.005

2.  Dearomatization reactions of aryl-substituted silaaziridines.

Authors:  Zulimar Nevárez; K A Woerpel
Journal:  J Org Chem       Date:  2008-09-03       Impact factor: 4.354

3.  The regio- and stereochemical course of reductive cross-coupling reactions between 1,3-disubstituted allenes and vinylsilanes: Synthesis of (Z)-dienes.

Authors:  Allan U Barlan; Glenn C Micalizio
Journal:  Tetrahedron       Date:  2010-06-26       Impact factor: 2.457

4.  Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C-H bond insertion cascades.

Authors:  Jiun-Le Shih; Santa Jansone-Popova; Christopher Huynh; Jeremy A May
Journal:  Chem Sci       Date:  2017-09-04       Impact factor: 9.825
  4 in total

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