| Literature DB >> 17696536 |
Mohammad N Noshi1, Ahmad El-awa, Eduardo Torres, Philip L Fuchs.
Abstract
Functionalized cyclic vinyl sulfones were directly converted to the "polarity reversed" vinyl phosphonates through an efficient one pot procedure. Ozonolysis of these vinyl sulfones and vinyl phosphonates furnish complementary sets of termini-differentiated ester-aldehydes. This strategy has been applied for preparation of segments needed for the synthesis of Aplyronine A. The scope and limitations of this transformation were defined.Entities:
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Year: 2007 PMID： 17696536 DOI： 10.1021/ja072890p
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419