Separation characteristics of wall-coated open-tubular columns for gas chromatography.

The application of the solvation parameter model for the classification of wall-coated open-tubular columns for gas chromatography is reviewed. A system constants database for 50 wall-coated open-tubular columns at five equally spaced temperatures between 60 and 140 degrees C is constructed and statistical and chemometric techniques used to identify stationary phases with equivalent selectivity, the effect of monomer chemistry on selectivity, and the selection of stationary phases for method development. The system constants database contains examples of virtually all commercially available common stationary phases.