Literature DB >> 17678285

Relationship between third-order nonlinear optical properties and magnetic interactions in open-shell systems: a new paradigm for nonlinear optics.

Masayoshi Nakano1, Ryohei Kishi, Suguru Ohta, Hideaki Takahashi, Takashi Kubo, Kenji Kamada, Koji Ohta, Edith Botek, Benoit Champagne.   

Abstract

Although most third-order nonlinear optical (NLO) materials are closed-shell singlet systems, this Letter theoretically shows that the third-order NLO properties are drastically enhanced in symmetric open-shell diradical systems with intermediate diradical character and further reveals that this enhancement is associated with the ferromagnetic and antiferromagnetic interactions. This new paradigm opens up a promising area for designing new third-order NLO materials.

Year:  2007        PMID： 17678285     DOI： 10.1103/PhysRevLett.99.033001

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN： 0031-9007            Impact factor:   9.161


  20 in total

1.  Design of Lewis acid-base complex: enhancing the stability and first hyperpolarizability of large excess electron compound.

Authors:  Fang Ma; Tifang Miao; Zhongjun Zhou; Dengming Sun
Journal:  J Mol Model       Date:  2013-11       Impact factor: 1.810

2.  The symmetric and asymmetric thiophene-fused benzocarborane: structures and first hyperpolarizabilities.

Authors:  Yong Li; Heng-Qing Wu; Hong-Liang Xu; Shi-Ling Sun; Zhong-Min Su
Journal:  J Mol Model       Date:  2013-06-22       Impact factor: 1.810

3.  The Effect of the different spin multiplicity on nonlinear optical properties of lithium decahydroborate dimers.

Authors:  Yong Li; Hong-Liang Xu; Rong-Lin Zhong; Shi-Ling Sun; Zhong-Min Su
Journal:  J Mol Model       Date:  2014-09-13       Impact factor: 1.810

4.  A theoretical study of alkaline-earthides Li(NH3)4M (M = Be, Mg, Ca) with large first hyperpolarizability.

Authors:  Linsheng Zhu; Kaijing Xue; Jianhua Hou
Journal:  J Mol Model       Date:  2019-05-08       Impact factor: 1.810

5.  Tuning the Diradical Character of Indolocarbazoles: Impact of Structural Isomerism and Substitution Position.

Authors:  Irene Badía-Domínguez; Sofia Canola; Víctor Hernández Jolín; Juan T López Navarrete; Juan C Sancho-García; Fabrizia Negri; M Carmen Ruiz Delgado
Journal:  J Phys Chem Lett       Date:  2022-06-23       Impact factor: 6.888

6.  Diindeno-fusion of an anthracene as a design strategy for stable organic biradicals.

Authors:  Gabriel E Rudebusch; José L Zafra; Kjell Jorner; Kotaro Fukuda; Jonathan L Marshall; Iratxe Arrechea-Marcos; Guzmán L Espejo; Rocío Ponce Ortiz; Carlos J Gómez-García; Lev N Zakharov; Masayoshi Nakano; Henrik Ottosson; Juan Casado; Michael M Haley
Journal:  Nat Chem       Date:  2016-05-23       Impact factor: 24.427

7.  Computational investigation on redox-switchable nonlinear optical properties of a series of polycyclic p-quinodimethane molecules.

Authors:  Yong-Qing Qiu; Wen-Yong Wang; Na-Na Ma; Cun-Huan Wang; Meng-Ying Zhang; Hai-Yan Zou; Peng-Jun Liu
Journal:  J Mol Model       Date:  2013-11-17       Impact factor: 1.810

8.  Third-Order Nonlinear Optical Properties of One-Dimensional Quinoidal Oligothiophene Derivatives Involving Phenoxyl Groups.

Authors:  Ryohei Kishi; Tsubasa Katsurayama; Shoki Ochi; Akihiro Makino; Naoyuki Matsushita; Michika Saito; Takanori Nagami; Jun-Ya Fujiyoshi; Masayoshi Nakano
Journal:  ChemistryOpen       Date:  2017-07-03       Impact factor: 2.911

9.  Role of Kekulé and Non-Kekulé Structures in the Radical Character of Alternant Polycyclic Aromatic Hydrocarbons: A TAO-DFT Study.

Authors:  Chia-Nan Yeh; Jeng-Da Chai
Journal:  Sci Rep       Date:  2016-07-26       Impact factor: 4.379

10.  Multiphoton harvesting metal-organic frameworks.

Authors:  Hong Sheng Quah; Weiqiang Chen; Martin K Schreyer; Hui Yang; Ming Wah Wong; Wei Ji; Jagadese J Vittal
Journal:  Nat Commun       Date:  2015-08-06       Impact factor: 14.919
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