Long-range correlation and charge transfer efficiency in substitutional sequences of DNA molecules.

We address the relation between long-range correlations and coherent charge transfer in substitutional DNA sequences using the transfer matrix approach. The substitutional sequences exhibit long-range correlations and show good transmittivity in comparison with uncorrelated random ones. It is found that the charge transfer efficiency varies for different substitutional sequences and many will present electronic delocalization in the system. Further, the resistivity for substitutional sequences may range from decreasing with the length, length independence, or increasing with the length. The conduction mechanisms of various behaviors observed for these sequences are analyzed.