Literature DB >> 17675687

The one-dimensional chain polymer of aqua(tyrosinato)zinc(II).

Dong Qing Li1, Jian Zhou, Xing Liu.   

Abstract

In the title compound, catena-poly[[aquazinc(II)]-micro(3)-tyrosinato], [Zn(C(9)H(7)NO(3))(H(2)O)](n), each Zn atom has a distorted square-pyramidal geometry comprised of three O atoms and one N atom from three tyrosinate (tyr) ligands, and one aqua ligand. Two inversion-related Zn(2+) ions are bridged by two O atoms from the phenolate groups of two tyr ligands to form a centrosymmetric dimeric unit, which can be described as a planar Zn(2)O(2) four-membered ring. These repeating dimeric units are arranged along the c axis to give a one-dimensional chain coordination polymer, in which the tyr ligand adopts an unusual chelating/bridging coordination mode.

Entities:  

Year:  2007        PMID: 17675687     DOI: 10.1107/S010827010703185X

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  2 in total

1.  Extended Absorption of Liothyronine from Poly-Zinc-Liothyronine: Results from a Phase 1, Double-Blind, Randomized, and Controlled Study in Humans.

Authors:  Alexandra M Dumitrescu; Erin C Hanlon; Marilyn Arosemena; Olga Duchon; Matthew Ettleson; Mihai Giurcanu; Antonio C Bianco
Journal:  Thyroid       Date:  2021-12-31       Impact factor: 6.568

2.  Metal Coordinated Poly-Zinc-Liothyronine Provides Stable Circulating Triiodothyronine Levels in Hypothyroid Rats.

Authors:  Rodrigo R Da Conceição; Gustavo W Fernandes; Tatiana L Fonseca; Barbara M L C Bocco; Antonio C Bianco
Journal:  Thyroid       Date:  2018-11       Impact factor: 6.568

  2 in total

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