Literature DB >> 17675682

Intramolecular interactions in micro-oxido-bis{bis[2-(dimethylaminomethyl)phenyl]stannol}.

Adina Rotar1, Richard A Varga, Cristian Silvestru.   

Abstract

The title compound, [Sn(2)(C(9)H(12)N)(4)O(OH)(2)], consists of two [2-(Me(2)NCH(2))C(6)H(4)](2)SnOH units bridged by an O atom located on a twofold rotation axis. The unique Sn atom is six-coordinated with a (C,N)(2)SnO(2) octahedral core, as a result of the strong intramolecular N-->Sn dative coordination trans to the Sn-O bonds [N-Sn-O = 170.24 (12) and 167.83 (10) degrees ]. Owing to the presence of intermolecular H...phenyl contacts, the molecules are arranged in a ladder-like structure.

Entities:  

Year:  2007        PMID: 17675682     DOI: 10.1107/S0108270107030156

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  2 in total

1.  Substitutional disorder in a hypervalent diorganotin(IV) dihalide.

Authors:  Adina Rotar; Richard A Varga; Cristian Silvestru
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2007-12-06

2.  Butyl-trichlorido{2-[(diisopropyl-ammonio)-meth-yl]phen-yl}tin(IV) dichloro-methane monosolvate.

Authors:  Adina Rotar; Richard A Varga; Malgorzata Staninska
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-12-11
  2 in total

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