| Literature DB >> 17672457 |
Olena Lukoyanova1, Claudia M Cardona, José Rivera, Leyda Z Lugo-Morales, Christopher J Chancellor, Marilyn M Olmstead, Antonio Rodríguez-Fortea, Josep M Poblet, Alan L Balch, Luis Echegoyen.
Abstract
Cycloaddition of bromomalonates to Y3N@C80 unexpectedly gave rise to fulleroid derivatives with unusually high stability. Complete characterization of these derivatives is described including X-ray crystallography, 1H NMR, 13C NMR, HMQC, UV-visible, HPLC, MALDI-MS, and electrochemistry. Density functional theory calculations are also presented, which provide a rationale for the formation of the fulleroid and reveal the underlying thermodynamic basis for their stability.Entities:
Year: 2007 PMID： 17672457 DOI： 10.1021/ja071733n
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419