Literature DB >> 17663549

Expedient method for the transmetalation of Zn(II)-centered salphen complexes.

Eduardo C Escudero-Adán1, Jordi Benet-Buchholz, Arjan W Kleij.   

Abstract

Various mono- and bis-ZnII complexes derived from salphen ligands have been conveniently transmetalated with a number of transition metal (TM) acetates (M=Ni, Pd, Mn) in THF to afford their respective TM-salphen counterparts in excellent isolated yields (80-100%). This new transmetalation procedure allows in situ switching between supramolecular and catalytic functions of the metallosalphen complex.

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Year:  2007        PMID: 17663549     DOI: 10.1021/ic701245r

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

1.  The ligand unwrapping/rewrapping pathway that exchanges metals in S-acetylated, hexacoordinate N2S2O2 complexes.

Authors:  J A Denny; W S Foley; A D Todd; M Y Darensbourg
Journal:  Chem Sci       Date:  2015-09-07       Impact factor: 9.825

  1 in total

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