Literature DB >> 17653371

Role of the isopropyl group in asymmetric autocatalytic zinc alkylations.

Jürgen Klankermayer1, Ilya D Gridnev, John M Brown.   

Abstract

The amplifying asymmetric autocatalysis discovered by Soai and co-workers is dependent on the unique steric properties of the isopropyl group.

Year:  2007        PMID: 17653371     DOI: 10.1039/b705978g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Asymmetric autocatalysis induced by chiral crystals of achiral tetraphenylethylenes.

Authors:  Tsuneomi Kawasaki; Mai Nakaoda; Nobuhiro Kaito; Taisuke Sasagawa; Kenso Soai
Journal:  Orig Life Evol Biosph       Date:  2009-11-13       Impact factor: 1.950

2.  Structural Contributions to Autocatalysis and Asymmetric Amplification in the Soai Reaction.

Authors:  Soumitra V Athavale; Adam Simon; K N Houk; Scott E Denmark
Journal:  J Am Chem Soc       Date:  2020-10-14       Impact factor: 15.419

3.  Rationalization of Asymmetric Amplification via Autocatalysis Triggered by Isotopically Chiral Molecules.

Authors:  Neil A Hawbaker; Donna G Blackmond
Journal:  ACS Cent Sci       Date:  2018-06-06       Impact factor: 14.553

4.  Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess.

Authors:  Arimasa Matsumoto; Takaaki Abe; Atsushi Hara; Takayuki Tobita; Taisuke Sasagawa; Tsuneomi Kawasaki; Kenso Soai
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-23       Impact factor: 15.336

  4 in total

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