Literature DB >> 17649993

Zirconium-catalyzed heterodehydrocoupling of primary phosphines with silanes and germanes.

Andrew J Roering1, Samantha N MacMillan, Joseph M Tanski, Rory Waterman.   

Abstract

Triamidoamine-supported zirconium complexes catalyze the heterodehydrocoupling of primary phosphines with silane and germanes. In this catalysis, P-Si or P-Ge products are observed exclusively with no competitive P-P bond formation. Phosphido complexes (N3N)ZrPHR (N3N = N(CH2CH2NSiMe3)33-, R = Ph, 2; Cy, 3) were observed to be the catalyst resting state, and complex 2 was structurally characterized.

Entities:  

Year:  2007        PMID： 17649993     DOI： 10.1021/ic7013144

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  5 in total

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Authors:  Erin M Leitao; Titel Jurca; Ian Manners
Journal:  Nat Chem       Date:  2013-10       Impact factor: 24.427

2.  Expanding Zirconocene Hydride Catalysis: In Situ Generation and Turnover of ZrH Catalysts Enabling Catalytic Carbonyl Reductions.

Authors:  Rebecca A Kehner; Matthew Christian Hewitt; Liela Bayeh-Romero
Journal:  ACS Catal       Date:  2022-01-18       Impact factor: 13.700

3.  {N,N-Bis[2-(trimethyl-silylamino)eth-yl]-N'-(trimethyl-silyl)ethane-1,2-diamin-ato(3-)-κN}methyl-zirconium(IV).

Authors:  Samantha N Macmillan; Joseph M Tanski; Rory Waterman
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-02-15

4.  Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV).

Authors:  Hannah Stafford; Thomas M Rookes; Elizabeth P Wildman; Gábor Balázs; Ashley J Wooles; Manfred Scheer; Stephen T Liddle
Journal:  Angew Chem Int Ed Engl       Date:  2017-05-26       Impact factor: 15.336

5.  Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts.

Authors:  Lipeng Wu; Vincent T Annibale; Haijun Jiao; Adam Brookfield; David Collison; Ian Manners
Journal:  Nat Commun       Date:  2019-06-26       Impact factor: 14.919
  5 in total

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