Polycyclic aromatic hydrocarbon generation behavior in the process of carbonization of wood.

PAH generation behaviors in carbonization were compared, using cypress, chestnut, and bamboo as samples. Generation of tarry matter was almost completed by the time the temperature reached 400 degrees C, while generation of PAHs continued until the temperature reached 1,000 degrees C. The weight of tarry matter per unit sample weight was large with bamboo, while the amount of PAHs was large with cypress. Of the 15 types of PAHs measured this time, the largest amount collected was fluorene, followed by phenanthrene and anthracene. The amount of PAHs generated accounted for 6 x 10(-6) to 16 x 10(-6) of the weight of the wood samples.