Literature DB >> 17637026

Base-free Mizoroki-Heck reaction catalyzed by rhodium complexes.

Rémi Martinez1, Florina Voica, Jean-Pierre Genet, Sylvain Darses.   

Abstract

A base-free rhodium-catalyzed Mizoroki-Heck (M-H) reaction using potassium aryltrifluoroborates as the arylating agent of alkenes and acetone as a green "oxidant" is described. Thanks to the ready availability of organoboranes, this reaction should constitute an interesting alternative to conventional M-H reactions using aryl halides.

Entities:  

Year:  2007        PMID: 17637026     DOI: 10.1021/ol071098q

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Copper-catalyzed oxidative Heck reactions between alkyltrifluoroborates and vinyl arenes.

Authors:  Timothy W Liwosz; Sherry R Chemler
Journal:  Org Lett       Date:  2013-06-04       Impact factor: 6.005

2.  Suzuki-Miyaura cross-coupling of brominated 2,1-borazaronaphthalenes with potassium alkenyltrifluoroborates.

Authors:  Gary A Molander; Steven R Wisniewski; Elham Etemadi-Davan
Journal:  J Org Chem       Date:  2014-10-30       Impact factor: 4.354

  2 in total

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