Literature DB >> 17622433

Light-fluorous safety-catch arylgermanes - exceptionally robust, photochemically activated precursors for biaryl synthesis by Pd(0) catalysed cross-coupling.

Alan C Spivey1, Chih-Chung Tseng, Joseph P Hannah, Christopher J G Gripton, Paul de Fraine, Nigel J Parr, Jan J Scicinski.   

Abstract

A new class of arylgermane derivative that participate efficiently in Pd(0)-catalysed cross-coupling reactions with aryl bromides following photochemical activation is described.

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Year:  2007        PMID： 17622433     DOI： 10.1039/b707517k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Fluoride-promoted cross-coupling of chloro(mono-, di-, or triphenyl)germanes with aryl halides in "moist" toluene. Multiple transfer of the phenyl group from organogermane substrates and comparison of the coupling efficiencies of chloro(phenyl)germanes with their corresponding stannane and silane counterparts.

Authors:  Jean-Philippe Pitteloud; Zun-Ting Zhang; Yong Liang; Laura Cabrera; Stanislaw F Wnuk
Journal:  J Org Chem       Date:  2010-11-10       Impact factor: 4.354

2.  Arylchlorogermanes/TBAF/"moist" toluene: a promising combination for Pd-catalyzed Germyl-Stille cross-coupling.

Authors:  Zun-Ting Zhang; Jean-Philippe Pitteloud; Laura Cabrera; Yong Liang; Myrdich Toribio; Stanislaw F Wnuk
Journal:  Org Lett       Date:  2010-02-19       Impact factor: 6.005

3.  Gold-Catalyzed C-H Functionalization with Aryl Germanes.

Authors:  Christoph Fricke; Amit Dahiya; William B Reid; Franziska Schoenebeck
Journal:  ACS Catal       Date:  2019-08-30       Impact factor: 13.084

4.  Modular and Selective Arylation of Aryl Germanes (C-GeEt3 ) over C-Bpin, C-SiR3 and Halogens Enabled by Light-Activated Gold Catalysis.

Authors:  Grant J Sherborne; Avetik G Gevondian; Ignacio Funes-Ardoiz; Amit Dahiya; Christoph Fricke; Franziska Schoenebeck
Journal:  Angew Chem Int Ed Engl       Date:  2020-06-12       Impact factor: 15.336
  4 in total

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