| Literature DB >> 17616141 |
Qadir K Timerghazin1, Gilles H Peslherbe, Ann M English.
Abstract
A resonance representation of the electronic structure of S-nitrosothiols as a combination of the conventional R-S-N=O structure, a zwitterionic structure R-S+=N-O-, and a RS-/NO+ ion pair is proposed. The resonance forms are employed to predict and rationalize the structural and conformational properties of RSNOs, their interaction with Lewis acids, and their overall chemical reactivity.Entities:
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Year: 2007 PMID： 17616141 DOI： 10.1021/ol0711016
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005