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Literature DB >> 17602594

An efficient one-pot synthesis of unsymmetrical ethers: a directly reductive deoxygenation of esters using an InBr3/Et3SiH catalytic system.

Norio Sakai¹, Toshimitsu Moriya, Takeo Konakahara.

Abstract

This study describes a novel one-pot procedure for a directly reductive conversion of the carbonyl function of esters to the corresponding ethers by Et3SiH in the presence of a catalytic amount of InBr3.

Entities: Chemical

Year: 2007 PMID： 17602594 DOI： 10.1021/jo070814z

Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354

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Cited

9 in total

1. Synthesis and antiproliferative activity of derivatives of the phyllanthusmin class of arylnaphthalene lignan lactones.

Authors: John L Woodard; Andrew C Huntsman; Pratiq A Patel; Hee-Byung Chai; Ragu Kanagasabai; Soumendrakrishna Karmahapatra; Alexandria N Young; Yulin Ren; Malcolm S Cole; Denisse Herrera; Jack C Yalowich; A Douglas Kinghorn; Joanna E Burdette; James R Fuchs
Journal: Bioorg Med Chem Date: 2018-03-23 Impact factor: 3.641

9. Chevalones H-M: Six New α-Pyrone Meroterpenoids from the Gorgonian Coral-Derived Fungus Aspergillus hiratsukae SCSIO 7S2001.

Authors: Xia-Yu Chen; Qi Zeng; Yu-Chan Chen; Wei-Mao Zhong; Yao Xiang; Jun-Feng Wang; Xue-Feng Shi; Wei-Min Zhang; Si Zhang; Fa-Zuo Wang
Journal: Mar Drugs Date: 2022-01-14 Impact factor: 5.118

9 in total

An efficient one-pot synthesis of unsymmetrical ethers: a directly reductive deoxygenation of esters using an InBr3/Et3SiH catalytic system.

1. Synthesis and antiproliferative activity of derivatives of the phyllanthusmin class of arylnaphthalene lignan lactones.

2. Transition metal photoredox catalysis of radical thiol-ene reactions.

3. Synthesis of Norbornane Bisether Antibiotics via Silver-mediated Alkylation.

4. Mycotoxins from Fusarium proliferatum: new inhibitors of papain-like cysteine proteases.

5. A cooperative N-heterocyclic carbene/chiral phosphate catalysis system for allenolate annulations.

Review 6. Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation.

7. Selective Hydrodeoxygenation of Esters to Unsymmetrical Ethers over a Zirconium Oxide-Supported Pt-Mo Catalyst.

8. Total Synthesis of Lignan Lactone (-)-Hinokinin.

9. Chevalones H-M: Six New α-Pyrone Meroterpenoids from the Gorgonian Coral-Derived Fungus Aspergillus hiratsukae SCSIO 7S2001.