Literature DB >> 17594044

Indium-bipyridine-catalyzed, enantioselective thiolysis of meso-epoxides.

Mecheril Valsan Nandakumar1, Andreas Tschöp, Harald Krautscheid, Christoph Schneider.   

Abstract

The indium-bipyridine-catalyzed, enantioselective ring-opening of meso-epoxides with aliphatic and aromatic thiols furnished 1,2-mercapto alcohols in good yields and excellent enantioselectivities; the crystal structure of the chiral catalyst reveals a pentagonal-bipyramidal coordination geometry around the indium center.

Entities:  

Year:  2007        PMID： 17594044     DOI： 10.1039/b703625f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

Review 1.  Recent trends in ring opening of epoxides with sulfur nucleophiles.

Authors:  Sajjad Ahmad; Ameer Fawad Zahoor; Syed Ali Raza Naqvi; Muhammad Akash
Journal:  Mol Divers       Date:  2017-11-14       Impact factor: 2.943

Review 2.  Synthesis and Application of the Transition Metal Complexes of α-Pyridinyl Alcohols, α-Bipyridinyl Alcohols, α,α'-Pyridinyl Diols and α,α'-Bipyridinyl Diols in Homogeneous Catalysis.

Authors:  Tegene Tole; Johannes Jordaan; Hermanus Vosloo
Journal:  Molecules       Date:  2018-04-12       Impact factor: 4.411

3.  Lithium BINOL phosphate catalyzed desymmetrization of meso-epoxides with aromatic thiols.

Authors:  Gajendrasingh Ingle; Michael G Mormino; Jon C Antilla
Journal:  Org Lett       Date:  2014-10-15       Impact factor: 6.005

Review 4.  β-Hydroxy sulfides and their syntheses.

Authors:  Mokgethwa Bruce Marakalala; Edwin M Mmutlane; Henok H Kinfe
Journal:  Beilstein J Org Chem       Date:  2018-07-05       Impact factor: 2.883
  4 in total

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