| Literature DB >> 17580978 |
Christopher Hardacre1, John D Holbrey, Mark Nieuwenhuyzen, Tristan G A Youngs.
Abstract
This Account describes experimental data used to understand the structure of ionic liquids and solute-solvent interactions of both molecular solutes and dissolved metal complexes. In general, the structures of the ionic liquids determined from experimental data show good agreement with both simulated structures and solid-state structures. For all ionic liquids studied, strong charge ordering is found leading to long-range order even in the presence of a solute. For dissolved metal complexes, the ionic liquid is not innocent and a clear dependence on the speciation is observed with variations in both the cation and anion.Entities:
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Year: 2007 PMID: 17580978 DOI: 10.1021/ar700068x
Source DB: PubMed Journal: Acc Chem Res ISSN: 0001-4842 Impact factor: 22.384