Literature DB >> 17580905

One-pot amidation of olefins through Pd-catalyzed coupling of alkylboranes and carbamoyl chlorides.

Yoshizumi Yasui1, Sayo Tsuchida, Hideto Miyabe, Yoshiji Takemoto.   

Abstract

A one-pot synthesis of C1-elongated amides starting from olefins and carbamoyl chlorides has been developed. Alkylboranes, generated by hydroboration of terminal olefins with 9-BBN-H, underwent smooth coupling with carbamoyl chlorides in the presence of palladium catalyst and Cs2CO3.

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Year:  2007        PMID： 17580905     DOI： 10.1021/jo070724u

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  4 in total

Review 1.  Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners.

Authors:  Ranjan Jana; Tejas P Pathak; Matthew S Sigman
Journal:  Chem Rev       Date:  2011-02-14       Impact factor: 60.622

2.  S(vi) in three-component sulfonamide synthesis: use of sulfuric chloride as a linchpin in palladium-catalyzed Suzuki-Miyaura coupling.

Authors:  Xuefeng Wang; Min Yang; Shengqing Ye; Yunyan Kuang; Jie Wu
Journal:  Chem Sci       Date:  2021-04-06       Impact factor: 9.825

3.  Enantioselective Hydrocarbamoylation of Alkenes.

Authors:  Sheng Feng; Yuyang Dong; Stephen L Buchwald
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-23       Impact factor: 16.823

Review 4.  Suzuki-miyaura cross-coupling in acylation reactions, scope and recent developments.

Authors:  Marco Blangetti; Heléna Rosso; Cristina Prandi; Annamaria Deagostino; Paolo Venturello
Journal:  Molecules       Date:  2013-01-17       Impact factor: 4.411
  4 in total

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