| Literature DB >> 17579760 |
Takanori Matsuda1, Sho Kadowaki, Masahiro Murakami.
Abstract
Dihydrosilanes undergo double trans-hydrosilylation with 1,4-diarylbuta-1,3-diynes in the presence of a cationic ruthenium catalyst to afford 2,5-diarylsiloles: in particular, 9-silafluorene is a good hydrosilylating agent to produce spiro-type siloles in good yield.Entities:
Year: 2007 PMID: 17579760 DOI: 10.1039/b703397d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222