Literature DB >> 17552567

Palladium(II)-catalyzed isomerization of olefins with tributyltin hydride.

In Su Kim1, Guang Ri Dong, Young Hoon Jung.   

Abstract

A new efficient method for the synthesis of geometrically pure (E)-alkenes from (Z)-alkenes is described. The reaction of aryl- or alkyl-substituted (Z)-alkenes with tributyltin hydride and triethylamine in the presence of a catalytic amount of palladium acetate afforded the corresponding (E)-alkenes in good yields.

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Year:  2007        PMID： 17552567     DOI： 10.1021/jo0705263

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  4 in total

1.  Controlling Selectivity for Cycloadditions of Nitrones and Alkenes Tethered by Benzimidazoles: Combining Experiment and Theory.

Authors:  Liping Meng; Selina C Wang; James C Fettinger; Mark J Kurth; Dean J Tantillo
Journal:  European J Org Chem       Date:  2009-04

2.  Selective cross-coupling of organic halides with allylic acetates.

Authors:  Lukiana L Anka-Lufford; Michael R Prinsell; Daniel J Weix
Journal:  J Org Chem       Date:  2012-11-06       Impact factor: 4.354

3.  Z-Selective Dienylation Enables Stereodivergent Construction of Dienes and Unravels a Ligand-Driven Mechanistic Dichotomy.

Authors:  Hang T Dang; Viet D Nguyen; Graham C Haug; Ngan T H Vuong; Hadi D Arman; Oleg V Larionov
Journal:  ACS Catal       Date:  2021-01-07       Impact factor: 13.084

4.  Sonogashira reaction of aryl and heteroaryl halides with terminal alkynes catalyzed by a highly efficient and recyclable nanosized MCM-41 anchored palladium bipyridyl complex.

Authors:  Bo-Nan Lin; Shao-Hsien Huang; Wei-Yi Wu; Chung-Yuan Mou; Fu-Yu Tsai
Journal:  Molecules       Date:  2010-12-10       Impact factor: 4.411
  4 in total

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