Literature DB >> 17551621

Can "microwave effects" be explained by enhanced diffusion?

Christian Antonio1, Rowan T Deam.   

Abstract

The "microwave effect" or non-thermal effects due to microwaves have been the subject of intense debate. This paper explores the following hypothesis: if the transport of an active species is a rate limiting step in a reaction, and if microwaves enhance the diffusion of that species, then the overall reaction rate would change under microwave heating compared with conventional heating. If the hypothesis is correct then it should be possible to pick those reactions that would speed up, slow down or stay the same, under microwave irradiation. One consequence of the hypothesis is that the equilibrium states (end point of the reactions) remain unchanged by microwave irradiation. The measurements and theory presented here strongly suggest that this hypothesis is correct.

Year:  2007        PMID: 17551621     DOI: 10.1039/b617358f

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN: 1463-9076            Impact factor:   3.676


  2 in total

1.  Specific electromagnetic effects of microwave radiation on Escherichia coli.

Authors:  Yury Shamis; Alex Taube; Natasa Mitik-Dineva; Rodney Croft; Russell J Crawford; Elena P Ivanova
Journal:  Appl Environ Microbiol       Date:  2011-03-04       Impact factor: 4.792

2.  Size-Dependent Microwave Heating and Catalytic Activity of Fine Iron Particles in the Deep Dehydrogenation of Hexadecane.

Authors:  Xiangyu Jie; Roujia Chen; Tara Biddle; Daniel R Slocombe; Jonathan Robin Dilworth; Tiancun Xiao; Peter P Edwards
Journal:  Chem Mater       Date:  2022-05-13       Impact factor: 10.508

  2 in total

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