Literature DB >> 17551175

Metallophilic interactions in iodido(2,2':6',2''-terpyridine)platinum(II) diiodidoaurate(I).

Christina S Angle1, Kathryn J Woolard, Michael I Kahn, James A Golen, Arnold L Rheingold, Linda H Doerrer.   

Abstract

In the title compound, [PtI(C(15)H(11)N(3))][AuI(2)], the [PtI(terpy)](+) cations (terpy is 2,2':6',2''-terpyridine) stack in pairs about inversion centers through Pt...Pt interactions of 3.5279 (5) A. The [AuI(2)](-) anions also exhibit pairwise stacking, with Au...I distances of 3.7713 (5) A. The [PtI(terpy)](+) cations and [AuI(2)](-) anions aggregate forming infinite arrays of stacked ...([[PtI(terpy)](+)...[PtI(terpy)](+)]...[[AuI(2)](-)...[AuI(2)](-)])... units.

Entities:  

Year:  2007        PMID: 17551175     DOI: 10.1107/S0108270107015843

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Bromido(2,2':6',2''-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate.

Authors:  Michael I Kahn; James A Golen; Arnold L Rheingold; Linda H Doerrer
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-08-26
  1 in total

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