Literature DB >> 17542594

Development of a catalytic aromatic decarboxylation reaction.

Joshua S Dickstein1, Carol A Mulrooney, Erin M O'Brien, Barbara J Morgan, Marisa C Kozlowski.   

Abstract

A palladium-catalyzed aromatic decarboxylation reaction has been developed. With electron-rich aromatic acids, the reaction proceeds efficiently under fairly mild conditions in good yields. The method was useful with complex functionalized substrates containing hindered carboxylic acids.

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Year:  2007        PMID: 17542594     DOI: 10.1021/ol070749f

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  14 in total

1.  Hydrodecarboxylation of Carboxylic and Malonic Acid Derivatives via Organic Photoredox Catalysis: Substrate Scope and Mechanistic Insight.

Authors:  Jeremy D Griffin; Mary A Zeller; David A Nicewicz
Journal:  J Am Chem Soc       Date:  2015-08-28       Impact factor: 15.419

2.  Pd-catalyzed decarboxylative Heck vinylation of 2-nitrobenzoates in the presence of CuF₂.

Authors:  Lukas J Gooßen; Bettina Zimmermann; Thomas Knauber
Journal:  Beilstein J Org Chem       Date:  2010-05-03       Impact factor: 2.883

3.  Mild aromatic palladium-catalyzed protodecarboxylation: kinetic assessment of the decarboxylative palladation and the protodepalladation steps.

Authors:  Joshua S Dickstein; John M Curto; Osvaldo Gutierrez; Carol A Mulrooney; Marisa C Kozlowski
Journal:  J Org Chem       Date:  2013-04-29       Impact factor: 4.354

4.  Perylenequinone natural products: evolution of the total synthesis of cercosporin.

Authors:  Barbara J Morgan; Carol A Mulrooney; Marisa C Kozlowski
Journal:  J Org Chem       Date:  2010-01-01       Impact factor: 4.354

5.  Perylenequinone natural products: enantioselective synthesis of the oxidized pentacyclic core.

Authors:  Carol A Mulrooney; Barbara J Morgan; Xiaolin Li; Marisa C Kozlowski
Journal:  J Org Chem       Date:  2010-01-01       Impact factor: 4.354

6.  Perylenequinone natural products: total syntheses of the diastereomers (+)-phleichrome and (+)-calphostin D by assembly of centrochiral and axial chiral fragments.

Authors:  Barbara J Morgan; Carol A Mulrooney; Erin M O'Brien; Marisa C Kozlowski
Journal:  J Org Chem       Date:  2010-01-01       Impact factor: 4.354

7.  Perylenequinone natural products: total synthesis of hypocrellin A.

Authors:  Erin M O'Brien; Barbara J Morgan; Carol A Mulrooney; Patrick J Carroll; Marisa C Kozlowski
Journal:  J Org Chem       Date:  2010-01-01       Impact factor: 4.354

8.  Design, synthesis, and investigation of protein kinase C inhibitors: total syntheses of (+)-calphostin D, (+)-phleichrome, cercosporin, and new photoactive perylenequinones.

Authors:  Barbara J Morgan; Sangeeta Dey; Steven W Johnson; Marisa C Kozlowski
Journal:  J Am Chem Soc       Date:  2009-07-08       Impact factor: 15.419

9.  Simple, Efficient and Controllable Synthesis of Iodo/Di-iodoarenes via Ipsoiododecarboxylation/Consecutive Iodination Strategy.

Authors:  Yun Yang; Lijuan Zhang; Guo-Jun Deng; Hang Gong
Journal:  Sci Rep       Date:  2017-01-16       Impact factor: 4.379

Review 10.  Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis.

Authors:  Gregory J P Perry; Igor Larrosa
Journal:  European J Org Chem       Date:  2017-04-26
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