Literature DB >> 17530074

A cavitand stabilizes the Meisenheimer complex of SNAr reactions.

Sara M Butterfield1, Julius Rebek.   

Abstract

A deep cavitand binds amine nucleophiles and accelerates their subsequent S(N)Ar reactions by solvating the intermediate Meisenheimer complex.

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Year:  2007        PMID: 17530074     DOI: 10.1039/b700319f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Reaction of isonitriles with carboxylic acids in a cavitand: observation of elusive isoimide intermediates.

Authors:  Per Restorp; Julius Rebek
Journal:  J Am Chem Soc       Date:  2008-08-13       Impact factor: 15.419

  1 in total

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