Literature DB >> 17501427

Ostwald ripening, chiral crystallization, and the common-ancestor effect.

Julyan H E Cartwright1, Oreste Piro, Idan Tuval.   

Abstract

We introduce an agent-based model for advection-mediated chiral autocatalysis in which we take into account dissolution-crystallization processes through Ostwald ripening. We demonstrate that the latter phenomenon is the key to explaining previously puzzling experimental results whereby complete chiral symmetry breaking is attained from an initially unbiased mixture of seed crystals. We show that this homochirality is achieved by what has been termed the common-ancestor effect: Ostwald ripening removes competing lineages, leaving only one common ancestor for the entire system.

Year:  2007        PMID: 17501427     DOI: 10.1103/PhysRevLett.98.165501

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  4 in total

1.  Thermodynamic mechanism for solution phase chiral amplification via a lattice model.

Authors:  Thomas G Lombardo; Frank H Stillinger; Pablo G Debenedetti
Journal:  Proc Natl Acad Sci U S A       Date:  2009-04-23       Impact factor: 11.205

2.  Beyond crystals: the dialectic of materials and information.

Authors:  Julyan H E Cartwright; Alan L Mackay
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2012-06-28       Impact factor: 4.226

3.  Spontaneous and directed symmetry breaking in the formation of chiral nanocrystals.

Authors:  Uri Hananel; Assaf Ben-Moshe; Haim Diamant; Gil Markovich
Journal:  Proc Natl Acad Sci U S A       Date:  2019-05-16       Impact factor: 11.205

4.  Runaway electrification of friable self-replicating granular matter.

Authors:  Julyan H E Cartwright; Bruno Escribano; Hinrich Grothe; Oreste Piro; C Ignacio Sainz Díaz; Idan Tuval
Journal:  Langmuir       Date:  2013-10-01       Impact factor: 3.882

  4 in total

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