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Literature DB >> 17488057

Nucleophilic dearomatizing (DNAr) reactions of aromatic C,H-systems. A mature paradigm in organic synthesis.

Fernando López Ortiz¹, María José Iglesias, Ignacio Fernandez, Carmen M Andújar Sanchez, Gloria Ruiz Gómez.

Abstract

Year: 2007 PMID： 17488057 DOI： 10.1021/cr030207l

Source DB: PubMed Journal: Chem Rev ISSN： 0009-2665 Impact factor: 60.622

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13 in total

Review 1. Dearomatization strategies in the synthesis of complex natural products.

Authors: Stéphane P Roche; John A Porco
Journal: Angew Chem Int Ed Engl Date: 2011-04-19 Impact factor: 15.336

2. Fused bicyclic piperidines and dihydropyridines by dearomatising cyclisation of the enolates of nicotinyl-substituted esters and ketones.

Authors: Heloise Brice; Jonathan Clayden; Stuart D Hamilton
Journal: Beilstein J Org Chem Date: 2010-03-02 Impact factor: 2.883

3. Dearomative dihydroxylation with arenophiles.

Authors: Emma H Southgate; Jola Pospech; Junkai Fu; Daniel R Holycross; David Sarlah
Journal: Nat Chem Date: 2016-08-22 Impact factor: 24.427

4. A Phosphine-Mediated Dearomative Skeletal Rearrangement of Dianiline Squaraine Dyes.

Authors: Emily P Bacher; Kevin J Koh; Antonio J Lepore; Allen G Oliver; Olaf Wiest; Brandon L Ashfeld
Journal: Org Lett Date: 2021-03-26 Impact factor: 6.005

5. Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies.

Authors: Eiji Yamamoto; Satoshi Ukigai; Hajime Ito
Journal: Chem Sci Date: 2015-03-02 Impact factor: 9.825

Nucleophilic dearomatizing (DNAr) reactions of aromatic C,H-systems. A mature paradigm in organic synthesis.

Review 1. Dearomatization strategies in the synthesis of complex natural products.

2. Fused bicyclic piperidines and dihydropyridines by dearomatising cyclisation of the enolates of nicotinyl-substituted esters and ketones.

3. Dearomative dihydroxylation with arenophiles.

4. A Phosphine-Mediated Dearomative Skeletal Rearrangement of Dianiline Squaraine Dyes.

5. Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies.

6. Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives.

7. Unusual biaryl torsional strain promotes reactivity in Cu-catalyzed Sommelet-Hauser rearrangement.

8. Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols.

9. Formal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process.

10. Synthesis and Facile Dearomatization of Highly Electrophilic Nitroisoxazolo[4,3-b]pyridines.