| Literature DB >> 17480087 |
Srinivasu Pothukanuri1, Nicolas Winssinger.
Abstract
The azide-based carbamate or carbonate protecting group (Azoc) shown above can be removed in less than 2 min under neutral conditions using trimethyl or tributyl phosphine as well as polymer-bound triphenyl phosphine. It was shown to be orthogonal to Fmoc and Mtt for peptide synthesis and to afford beta-glycoside with a 2-aminoglucosyl donor by virtue of the neighboring group participation.Entities:
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Year: 2007 PMID: 17480087 DOI: 10.1021/ol0707160
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005