Literature DB >> 17447779

Size effect of encaged clusters on the exohedral chemistry of endohedral fullerenes: a case study on the pyrrolidino reaction of ScxGd3-xN@C80 (x = 0-3).

Ning Chen1, Er-Yun Zhang, Kai Tan, Chun-Ru Wang, Xin Lu.   

Abstract

We report a combined experimental and theoretical investigation on the regiochemistry of a series of TNT endohedral fullerenes ScxGd3-xN@C80 (x = 0-3) in 1,3-dipolar cycloadditions, which demonstrates that the regioselectivity of the TNT-based endohedral fullerenes ScxGd3-xN@C80 (x = 0-3) in the exohedral cycloadditions depends remarkably on the size of the encaged cluster.

Entities:  

Year:  2007        PMID： 17447779     DOI： 10.1021/ol070654d

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  Biomedical activities of endohedral metallofullerene optimized for nanopharmaceutics.

Authors:  Jie Meng; Dong-liang Wang; Paul C Wang; Lee Jia; Chunying Chen; Xing-Jie Liang
Journal:  J Nanosci Nanotechnol       Date:  2010-12

2.  Methane as a Selectivity Booster in the Arc-Discharge Synthesis of Endohedral Fullerenes: Selective Synthesis of the Single-Molecule Magnet Dy2TiC@C80 and Its Congener Dy2TiC2@C80.

Authors:  Katrin Junghans; Christin Schlesier; Aram Kostanyan; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Sandra Schiemenz; Rasmus Westerström; Thomas Greber; Bernd Büchner; Alexey A Popov
Journal:  Angew Chem Int Ed Engl       Date:  2015-09-09       Impact factor: 15.336

3.  Magnetic hysteresis in self-assembled monolayers of Dy-fullerene single molecule magnets on gold.

Authors:  C-H Chen; D S Krylov; S M Avdoshenko; F Liu; L Spree; R Westerström; C Bulbucan; M Studniarek; J Dreiser; A U B Wolter; B Büchner; A A Popov
Journal:  Nanoscale       Date:  2018-06-21       Impact factor: 7.790

4.  Highly regioselective complexation of tungsten with Eu@C82/Eu@C84: interplay between endohedral and exohedral metallic units induced by electron transfer.

Authors:  Lipiao Bao; Pengyuan Yu; Ying Li; Changwang Pan; Wangqiang Shen; Peng Jin; Shuquan Liang; Xing Lu
Journal:  Chem Sci       Date:  2019-04-26       Impact factor: 9.825

5.  Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism.

Authors:  Ariane Brandenburg; Denis S Krylov; Alexander Beger; Anja U B Wolter; Bernd Büchner; Alexey A Popov
Journal:  Chem Commun (Camb)       Date:  2018-09-20       Impact factor: 6.222

6.  Synthesis and characterization of carbene derivatives of Th@C 3v(8)-C82 and U@C 2v(9)-C82: exceptional chemical properties induced by strong actinide-carbon cage interaction.

Authors:  Xinye Liu; Bo Li; Wei Yang; Yang-Rong Yao; Le Yang; Jiaxin Zhuang; Xiaomeng Li; Peng Jin; Ning Chen
Journal:  Chem Sci       Date:  2020-12-21       Impact factor: 9.825
  6 in total

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