Literature DB >> 17435293

Overlooked problems in manifold twins: twin misfit in zero-obliquity TLQS twinning and twin index calculation.

Massimo Nespolo1, Giovanni Ferraris.   

Abstract

It is shown that the twin index n calculated, according to Friedel, as a function of the indices (hkl) and [uvw] of the lattice plane and lattice direction defining the cell of the twin lattice applies only to twofold twins, i.e. twins where the twin element is of order 2. For manifold twins, where the twin operation is a three-, four- or sixfold (direct or inverse) rotation, it is shown that the generalized formula becomes n=NXi/xi, where N is the number of lattice planes of the (hkl) family passing within the cell of the twin lattice, Xi the two-dimensional coincidence index for a plane of the (hkl) family and xi the number of planes out of N of that family that are partially restored by the twin operation. The existence of twin lattice quasi-symmetry (TLQS) twins with zero-obliquity in manifold twins leads to the introduction of a new parameter as a general measure of the pseudo-symmetry of TLQS rotation twins: the twin misfit delta, defined as the distance between the first nodes along the two shortest directions in the plane of LT (quasi-)perpendicular to the twin axes that are quasi-restored by the twin operation. Taking the example of staurolite twins, several inconsistencies in the treatment of manifold twins are pointed out.

Entities:  

Year:  2007        PMID: 17435293     DOI: 10.1107/S0108767307012135

Source DB:  PubMed          Journal:  Acta Crystallogr A        ISSN: 0108-7673            Impact factor:   2.290


  2 in total

1.  Analysis of the structural continuity in twinned crystals in terms of pseudo-eigensymmetry of crystallographic orbits.

Authors:  Mohamed Amine Marzouki; Bernd Souvignier; Massimo Nespolo
Journal:  IUCrJ       Date:  2013-10-18       Impact factor: 4.769

2.  Pathological macromolecular crystallographic data affected by twinning, partial-disorder and exhibiting multiple lattices for testing of data processing and refinement tools.

Authors:  Ivan Campeotto; Andrey Lebedev; Antoine M M Schreurs; Loes M J Kroon-Batenburg; Edward Lowe; Simon E V Phillips; Garib N Murshudov; Arwen R Pearson
Journal:  Sci Rep       Date:  2018-10-05       Impact factor: 4.379

  2 in total

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