Literature DB >> 17392965

Silver-catalyzed [2,3]-rearrangement of halonium ylides derived from allyl and propargyl halides and alkyl diazoacetates.

Pasupathy Krishnamoorthy1, R Greg Browning, Shreeyukta Singh, Rasapalli Sivappa, Carl J Lovely, H V Rasika Dias.   

Abstract

A silver(I) complex derived from a polyfluorinated tris(pyrazolyl)borate effectively catalyzes carbene transfer to allylic and propargylic halides, leading to the formation of alpha-haloacetate derivatives.

Entities:  

Year:  2007        PMID： 17392965     DOI： 10.1039/b608266a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Ligand-Controlled Regiodivergence in the Copper-Catalyzed [2,3]- and [1,2]-Rearrangements of Iodonium Ylides.

Authors:  Bin Xu; Uttam K Tambar
Journal:  J Am Chem Soc       Date:  2016-09-12       Impact factor: 15.419

2.  Copper-Catalyzed Enantio-, Diastereo-, and Regioselective [2,3]-Rearrangements of Iodonium Ylides.

Authors:  Bin Xu; Uttam K Tambar
Journal:  Angew Chem Int Ed Engl       Date:  2017-07-17       Impact factor: 15.336

3.  Copper-catalyzed [1,2]-rearrangements of allylic iodides and aryl α-diazoacetates.

Authors:  Bin Xu; Jackson Gartman; Uttam K Tambar
Journal:  Tetrahedron       Date:  2017-01-25       Impact factor: 2.457
  3 in total

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