Literature DB >> 17389992

Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes.

Richard Frantz1, Christopher S Grange, Nawal K Al-Rasbi, Michael D Ward, Jérôme Lacour.   

Abstract

The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co(4)(L)(6)(BF(4))](7+) leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.

Entities:  

Year:  2007        PMID: 17389992     DOI: 10.1039/b618092b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  AuICl-bound N-heterocyclic carbene ligands form MII4(LAuCl)6 integrally gilded cages.

Authors:  William J Ramsay; Jonathan A Foster; Katharine L Moore; Tanya K Ronson; Raphaël J Mirgalet; David A Jefferson; Jonathan R Nitschke
Journal:  Chem Sci       Date:  2015-09-24       Impact factor: 9.825

  1 in total

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