Literature DB >> 17355157

Mechanism of ultraviolet bonding of perfluoropolyethers revisited.

Xing-Cai Guo1, Robert J Waltman.   

Abstract

The mechanism of ultraviolet (UV) bonding of perfluoropolyether (PFPE) boundary lubricants on magnetic disk surfaces is re-examined experimentally. It is found that UV-emitted photoelectrons may contribute a negligible part, and instead the UV bonding correlates with the direct photodissociation of PFPE molecules. The UV-induced photodissociation is demonstrated to occur almost randomly on the PFPE molecular chain. The contribution from photooxidation is eliminated under nitrogen purge.

Entities:  

Year:  2007        PMID: 17355157     DOI: 10.1021/la063211b

Source DB:  PubMed          Journal:  Langmuir        ISSN: 0743-7463            Impact factor:   3.882


  1 in total

1.  Strong fragmentation processes driven by low energy electron attachment to various small perfluoroether molecules.

Authors:  C Mitterdorfer; A Edtbauer; S Karolczak; J Postler; D Gschliesser; S Denifl; E Illenberger; P Scheier
Journal:  Int J Mass Spectrom       Date:  2011-09-01       Impact factor: 1.986

  1 in total

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